Weird and Wonderful Water

Water is the stuff of life. We can't live without it, and neither can the rest of the food chain. The search for extraterrestrial life hinges on whether or not a planet or moon contains liquid water, but that assumes that any life off Earth is the same as Earth-based life. This week we'll take a look about what makes water so special and how it keeps all of us alive.

Water, the most abundant substance on Earth.
Unless air is more abundant.

Water is unique among all chemicals (yes, it's a chemical) because it is the only one found in solid, liquid, and gas states naturally on Earth. While ice and water vapor aren't basic requirements for life, they are key components of the water cycle. Water stored as snow and ice in the mountains is slowly released during the dry summers in the American west, meaning a steady flow in rivers throughout the year. Clouds made of water vapor transport precipitation over long distances. On top of that, ice and steam make modern life more convenient- think food storage and electricity generation.

Winter snow waiting for the spring melt, March 2016

Typically, solids are more dense than liquids, which in turn are more dense than gases. Water flips this around, as ice is less dense than liquid water. If you freeze a container of water, you'll notice that the ice fills more of the container than the water did. This is why your frozen pipes burst in winter. The expansion of water as it freezes is a visual of the density decreasing. Because ice is less dense than water, it floats. Because ice floats, it forms on the surface of lakes and other bodies. This allows aquatic life to survive. If water froze from the bottom up, everything would either freeze in place, or eventually be exposed on the surface.

Molecular structure of liquid water and ice (Mountain Empire CC)

Water has adhesive and cohesive properties. Water molecules stick to each other (cohesion) and other substances (adhesion). Adhesion causes capillary action. This is the movement that is responsible for plants being able to absorb water in the ground through their roots, up the stem, and to the highest leaves. Cohesion also contributes to surface tension. Water molecules on the surface are more tightly packed and can resist pressure from outside forces. This allows objects to float. Water striders can stand on the surface because of surface tension.

Water strider striding water (National Wildlife Federation)

Water has a high specific heat. Specific heat is the amount of energy needed to raise the temperature of a gram of water by one degree Celsius. Because it takes a lot of energy (1 calorie per gram) to heat water, it takes a lot of heat to boil water. Ocean life appreciates not being boiled. Water also holds onto heat it absorbs and releases it slowly, moderating Earth's temperature and making the seasonal changes gradual.

Water dissolves more substances than any other. The polar structure of the water molecule. The positive hydrogen end will attract negative ions, while the negative oxygen ends attract positive ions. Water's solvency is important for plants and animals to absorb nutrients, and for animals to flush waste from their bodies. Nonpolar substances like fats do not dissolve. That's where the saying "Oil and water don't mix" comes from. Less dense fats will float on top of water, and with some skill they can be separated.

Next time you take a drink, raise a glass in appreciation of water. Without it, your drink wouldn't be here and neither would you. This week's information comes from USGS and Mountain Empire Community College.

A Breath of Fresh Air

If you like fresh air, you're probably a big fan of the Clean Air Act and its amendments. While the air in many places is far from ideal, prior to federal legislation it was downright deadly in American cities. A clear gray sky on a summer's day in Philadelphia is a little off-putting, but it beats a smothering fog in the valleys outside Pittsburgh. After the deadly Donora smog in 1948 killed 20 and sickened thousands of others. Federal investigators were asked to come in, and determined that air pollution was in fact the killer, among other factors.

Donora smog, 1948 (Smithsonian)

The government prefers to take baby steps when implementing positive change, rather than jumping in feet first, and tackling air pollution is no exception. The first step came in 1955 with the Air Pollution Control Act, which provided funding for research and led to the Clean Air Act of 1963 and Air Quality Act of 1967. These provided the first air quality monitoring.

Pittsburgh in the 1940s (Citylab)

The Clean Air Act of 1970 was a major step forward. It developed limits on pollution and expanded federal enforcement powers. Among the controls included were auto emissions. States were mandated to implement plans to reduce pollution.
The Amendments of 1990 aimed to reduce air pollution linked to acid rain and ozone depletion.
Looking at a picture of the summer sky over Los Angeles, it might be hard to believe the Clean Air Act is working. However, the number of ugly sky days is lower than prior to enactment. Air quality monitors in California frequently show poor quality, and geography is partly to blame. Ocean breezes carry pollution as far as the mountains, where it gets stuck and sometimes builds up for days.

Los Angeles skyline (LAist)

Acid rain has been reduced as a result on the 1990 amendments. pH testing has shown freshwater pH levels in many areas have risen closer to neutral 7. Pure water is neutral, but in nature, water is rarely pure. Pristine rain is slightly acidic because of carbon dioxide in the atmosphere forming carbonic acid. However, the lowered pH in rivers and lakes nationwide was far lower than caused by carbonic acid. Targets of the 1990 amendments were nitrogen oxides (NOx) and sulfur dioxide (SO2). Emissions have been greatly reduced over the last 30 years, and ecosystems are continuing to slowly recover.

Visuals of higher pH meaning less acidic water samples
(National Atmospheric Deposition Program)

Information this week comes the EPA (Clean Air Act overview), Smithsonian Magazine (Donora), and more EPA (acid rain). For a great visual on showing higher pH and lower NOx and SO2, check out the National Atmospheric Deposition Program.

EPA: https://www.epa.gov/clean-air-act-overview/evolution-clean-air-act
Smithsonian: https://www.smithsonianmag.com/history/deadly-donora-smog-1948-spurred-environmental-protection-have-we-forgotten-lesson-180970533/
EPA: https://www.epa.gov/airmarkets/acid-rain-program
nm1 LAist: https://laist.com/2018/10/30/why_las_smog_has_been_extra_smoggy.php
nm2 Citylab: https://www.citylab.com/design/2012/06/what-pittsburgh-looked-when-it-decided-it-had-pollution-problem/2185/
nm3 Smithsonian
nm4 National Atmospheric Deposition Program http://nadp.slh.wisc.edu/data/animaps.aspx

More Winter Adaptations

The dead of winter is nigh upon us. It had been relatively mild where I am, despite a colder fall than usual. Unlike this time last year, we are having some temperatures above freezing. I deal with the cold by putting on this flannel,

but how are some more of out animal friends coping?
The wood frog survives by going into suspended animation while buried in mud or leaf litter. For all intents and purposes, it is dead. It survives the cold (and insect-free) winter because it produces a natural antifreeze that keep the water in its cells from freezing and bursting.

Wood frog (MN Dept. of Natural Resources)

Deciduous trees also have to work around internal ice causing cells to burst. In late summer they prepare for winter by shedding their leaves, which reduces the surface area that snow and ice can accumulate on. That protects branches from breaking. They also drastically reduce water consumption. It won't be needed without photosynthesis happening, and less water stores in the trunk is less risk of water freezing and causing a rupture.

Leafless trees that gave up drinking

Snapping turtles survive by spending the winter underwater. Lucky for them, water freezes from the top down rather than from the bottom up. The cold water and lack of oxygen may seem less than ideal living conditions but somehow the turtles survive by changing their blood chemistry to compensate for increasing levels of acid.

Snapping Turtle (Missouri Dept. of Conservation)

Insects also are able to adapt to winter conditions. I always assumed they flew south ahead of the birds or just did when I was younger. Some use the same antifreeze method as the wood frog. Others allow themselves to freeze without becoming ice, a process known as supercooling. Supercooled fluids remain liquid at temperatures below freezing. But the risk is always there that a single particle could allow ice crystals to form. Once that happens it's game over.  The fluid instantly iced over, killing the insect.

Supercooled stonefly (Scientific American)

While you are enjoying the snow from inside your cozy house, just be thankful you don't have to rely on chemistry or dehydration to make it through the winter. And next time you need a snack, it probably won't be your last for a few months.
This week's information comes from the Minnesota Department of Natural Resources and Bernd Heinrich's book "Winter World".

Superfund Site

While I was working toward my environmental science one of my classes was Environmental Law and Policy. For one of our assignments we had to research a Superfund site and present to the class. The site I chose was less than a mile as the crow flies from where I grew up. At that time, EPA hadn’t begun work on the site. Last year after moving back to Pennsylvania, I attended an EPA meeting on the status of the cleanup. This year, as work nears completion, I was able to tour the site with EPA’s Tim Gallagher.

Contrary to what you might think, not all Superfund sites are full of leaking drums of glowing green radioactive waste. The Watson-Johnson property was a landfill from the 50s to the 70s, then forgotten about. In the late 90s, water testing revealed several contaminants in the groundwater. One of the town wells for the water supply was closed. The solution the EPA came up with was to cap the landfill and use chemical injection to neutralize the contaminants in the groundwater.

Watson Johnson landfill site. The geosynthetic is
buried under 18 inches of soil here.

Capping the landfill is a common practice at sites like this. Why not remove the waste? Odds are, everything would just be taken out of the ground and buried in another landfill somewhere else. One oozing container was discovered and removed from the site, but otherwise it was all collected together and capped. The cap uses a layer of compacted clay soil, a waterproof synthetic fabric, more soil, and vegetation. The purpose of the cap is to keep the waste contained and keep water out, preventing anything from seeping into the groundwater.  Water drains to wetlands, ponds, and level spreaders. Level spreaders are cement cisterns that capture water and allow it to overflow and slowly spread away from the site.

Drainage swale around the outside of the capped landfill.
Grass seed has already been spread inside it.

Level spreader beyond the edge of the capped landfill

The soil above and around the cap is contoured to divert surface water away from the cap. There are natural wetlands on site, as well as new artificial wetlands created to contain and disperse runoff. The cap itself layered in a way that creates pathways for gases flow towards several vents. Because they site was once open but now is closed with those release points, concentrations are higher. Methane has been noted at the vents, but not volatile organic compounds (VOCs).

Gas vent. No monitors are attached.

Monitoring and injection wells reach the groundwater. Sodium permanganate is injected to react with the chemicals in the water. The reaction breaks down the chemicals (including the sodium permanganate) into harmless elements like oxygen and hydrogen. Monitoring wells are set up to test the levels of chemicals in the water. Injections will stop once the concentration goes below 100 parts per billion. At that point, EPA will begin bioremediation. Microscopic critters that eat the contaminants will be injected to the groundwater to bring the contaminants down even further.

Work on the site is nearing completion. Despite a cold winter and rainy summer, work is only two months behind schedule. Workers are currently adding a layer of topsoil six inches deep on top of the cover soil. Once topsoil is in place, it will be seeded with native grasses. Around the cap, workers are setting up deer fence to protect new trees that will be going in. Landscaping was supposed to start last week but was delayed by heavy rain.

EPA will continue to monitor the site for a year after completion, before turning that duty over to the state. Future plans include nesting boxes for swallows and bats. The new trees will create a nice matrix with the older existing woods on the edge of the site, which should attract songbirds that prefer new growth. The site is privately owned, so it will not become a park like old landfills in other areas. However, development will be limited by cap so it will likely remain a nice green oasis as the area becomes increasingly more urbanized.

For more information visit the EPA's Watson Johnson website. Special thanks to Tim Gallagher for taking time out of his day to show me around.

The Good Old Days

This week’s adventure takes a peek at the past. Earth was a vastly different place in the good old days. Dinosaurs ruled and everything was just a bigger, sabre-toothed version of the critters we have today. OK, maybe not the bigger, pointier critters. But scientists can tell us a lot about the way things used to be by looking at the fossil record.

Fossils are like prehistoric pictures. They form when dead organic material is slowly replaced by mineral material. Not everything that ever died was destined to become a fossil; only in certain conditions could the transition take place. Being in a situation without oxygen would’ve helped your cause if you were hoping to fossilize. Oxygen is a requirement for decomposition. If you’re decomposing, you won’t leave behind anything to fossilize. 

Little worm fossils imprinted on a rock

Usually when you think of fossils you think of huge dinosaur bones. There are other types of fossils too. Footprints in dried mud that later turned to stone can be found in Alaska and Africa.

Dinosaur footprint found at Denali National Park (NPS)

Imprints of shells in rock are mountains that used to be sea floor. One wound up in my back yard in Pennsylvania. One day a dead plant was buried in between layers of sediment that hardened into rock. Years later, I squeezed that rock and found black images of that plant inside the rock. Whole trees can be fossilized into petrified wood. Ancient insects trapped in tree sap that hardened into amber are also fossils.

A rock full of shells from my back yard

Plant fossils inside a piece of sedimentary rock

If you want to find some fossils, you don’t need to be a paleontologist or geologist. All it takes is a little luck and some sedimentary rock. Igneous rock is volcanic in nature, so that won’t be likely to preserve any critters. Metamorphic rock is rock that has changed from heat and pressure, so no luck there either. But sedimentary rock is just dirt that compacted into rocks. If you go on a fossil hunt, respect private property and remember not to take anything from or do any damage to national parks.

Petrified wood- looking at the rough bark

Petrified wood- look closely and you can see the grains

Ant trapped in amber (Smithsonian)

Dead Zones

This week we’re taking a look at a problematic summer tradition: hypoxic dead zones. These are marine or aquatic areas that don’t have enough oxygen to support life. The most famous is probably the dead zone in the Gulf of Mexico. Let’s look at dead zones, how they form, and what you can do to help prevent them.

The most common cause of dead zones is excessive nutrient runoff. Nutrients in this case are nitrogen and phosphorus, nutrients from plants. The main source of this nutrient runoff is agriculture, but it can also come from detergents, animal waste, and untreated sewage.

Gulf of Mexico dead zone (Digital Journal)

The nutrient overload leads to a sudden population boom in the local algae community. It seems paradoxical that algae, which produces oxygen, leads to an area without oxygen. First, when a large mat of algae covers the water’s surface it prevents oxygenation at the water/air interface. Then, when the algae dies and decomposes, that is where the oxygen disappears to. Mobile critters like fish can move to more oxygenated areas to survive, but something that can’t move or is very slow like a starfish or sea urchin will suffocate unless the situation clears up.

How a dead zone forms (Gulf Hypoxia)

Sometimes the algae bloom is of a type that produces toxins. Sometimes the toxins cause fish kills. Shellfish can absorb the toxins through filter feeding and pass them on to predators and people. Algae toxins can even threaten public drinking water.

A closer look at an algae bloom (NOAA)

How can you help? Trying to stop non-point pollution seems hopeless, but if everyone ups their game a little bit it adds up and makes a difference. Simple steps you can take at home include limiting the amount of fertilizer you use for your lawn and garden, cleaning up after your pup, and washing your car in the grass rather than the driveway or street. Reducing fertilizer use reduces the amount of excess nitrogen and phosphorus washing into the storm drain and out to sea. If you’re already doing that, buy organic produce which doesn’t use any fertilizer or pesticide. Picking up your dog poop keeps the nitrogen and phosphorus from that source out of the system as well. Washing your car in the yard lets the phosphorus in the detergent soak into the yard rather than washing into the storm drain. Every little bit helps.

This week's information comes from the EPA.